Oligomerisation of ethene by new palladium iminophosphine catalysts

被引：84

作者：

van den Beuken, EK

Smeets, WJJ

Spek, AL

Feringa, BL

机构：

[1] Univ Groningen, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands

[2] Univ Utrecht, Dept Crystal & Struct Chem, Bijvoet Ctr Biomol Res, NL-3584 CH Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 02期

关键词：

D O I：

10.1039/a707495f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oligomerisation of ethene in polar solvents at higher temperatures is achieved using new palladium iminophosphine catalysts and the oligomer selectivity can be controlled by the nature of the ligand substituents.

引用

页码：223 / 224

页数：2

共 24 条

[1] Late transition metal complexes: Catalysts for a new generation of organic polymers [J].

AbuSurrah, AS ;

Rieger, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (21) :2475-2477

[2] STEREOSPECIFIC OLEFIN POLYMERIZATION WITH CHIRAL METALLOCENE CATALYSTS [J].

BRINTZINGER, HH ;

FISCHER, D ;

MULHAUPT, R ;

RIEGER, B ;

WAYMOUTH, RM .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1995, 34 (11) :1143-1170

[3] OSCILLATING STEREOCONTROL - A STRATEGY FOR THE SYNTHESIS OF THERMOPLASTIC ELASTOMERIC POLYPROPYLENE [J].

COATES, GW ;

WAYMOUTH, RM .

SCIENCE, 1995, 267 (5195) :217-219

[4] NEW NEUTRAL AND IONIC METHYL AND CHLORO PALLADIUM AND PLATINUM COMPLEXES CONTAINING HEMILABILE PHOSPHORUS NITROGEN LIGANDS - STUDY OF THE INSERTION OF CARBON-MONOXIDE INTO THE METAL METHYL BOND [J].

DEKKER, GPCM ;

BUIJS, A ;

ELSEVIER, CJ ;

VRIEZE, K ;

VANLEEUWEN, PWNM ;

SMEETS, WJJ ;

SPEK, AL ;

WANG, YF ;

STAM, CH .

ORGANOMETALLICS, 1992, 11 (05) :1937-1948

[5] Mechanistic studies of catalytic olefin dimerization reactions using electrophilic eta(3)-allyl-palladium(II) complexes [J].

DiRenzo, GM ;

White, PS ;

Brookhart, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (26) :6225-6234

[6] EFFICIENT PALLADIUM CATALYSTS FOR THE CARBONYLATION OF ALKYNES [J].

DRENT, E ;

ARNOLDY, P ;

BUDZELAAR, PHM .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 455 (1-2) :247-253

[7] Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide [J].

Drent, E ;

Budzelaar, PHM .

CHEMICAL REVIEWS, 1996, 96 (02) :663-681

[8] EFFICIENT PALLADIUM CATALYSTS FOR THE COPOLYMERIZATION OF CARBON-MONOXIDE WITH OLEFINS TO PRODUCE PERFECTLY ALTERNATING POLYKETONES [J].

DRENT, E ;

VANBROEKHOVEN, JAM ;

DOYLE, MJ .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 417 (1-2) :235-251

[9] OPPORTUNITIES IN HOMOGENEOUS CATALYSIS [J].

DRENT, E .

PURE AND APPLIED CHEMISTRY, 1990, 62 (04) :661-669

[10]

DRENT E, 1989, Patent No. 852010187

← 1 2 3 →