Picturing molecular femtosecond processes through an ultra-fast controllable X-ray shutter

被引：6

作者：

Baev, A ^{[1
]}

Salek, P

Gelmukhanov, FK

Ågren, H

de Brito, AN

Björneholm, O

Svensson, S

机构：

[1] Royal Inst Technol, SCFAB, S-10691 Stockholm, Sweden

[2] Univ Uppsala, Dept Phys, S-75121 Uppsala, Sweden

[3] Univ Brasilia, Inst Phys, BR-70910900 Brasilia, DF, Brazil

来源：

CHEMICAL PHYSICS | 2003年 / 289卷 / 01期

关键词：

D O I：

10.1016/S0301-0104(02)00796-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We show that frequency detuning in a resonant X-ray scattering experiment acts as an X-ray camera shutter by regulating the duration time of the scattering process. The camera shutter can be used to select processes at different time scales for observation. This is illustrated by a resonant Auger study of the ultra-fast dissociation of the core-excited HF molecule. We present experimental results and first principle simulations of the molecular fraction in the resonant Auger spectra of HF which is a dynamical parameter that well illustrates X-ray shutter controlled dissociation. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：51 / 56

页数：6

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