An enantioselective CpRu-catalyzed Carroll rearrangement

被引：63

作者：

Constant, Samuel ^{[1
]}

Tortoioli, Simone ^{[1
]}

Mueller, Jessica ^{[1
]}

Lacour, Jerome ^{[1
]}

机构：

[1] Univ Geneva, Dept Chim Organ, CH-1211 Geneva 4, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 12期

关键词：

C-C coupling; enantioselectivity; N ligands; rearrangement; ruthenium;

D O I：

10.1002/anie.200604573

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Simple ligands, catalyst, and conditions: The combination of readily prepared unsymmetrical pyridine-imine ligands and [CpRu(CH3CN)3][PF6] (Cp = C5H 5) affords regio- and enantioselective Carroll rearrangements (see scheme; b/l = branched-to-linear ratio). This reaction represents the first example of Ru-catalyzed enantioselective C-C bond-forming allylic substitution. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2082 / 2085

页数：4

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