Laser-powered homogeneous pyrolysis of 4-silaspiro[3,3]heptane. A source for 2-silaallene and its polymer

被引：20

作者：

Urbanova, M

Volnina, EA

Guselnikov, LE

Bastl, Z

Pola, J

机构：

[1] ACAD SCI CZECH REPUBL,INST CHEM PROC FUNDAMENTALS,CR-16502 PRAGUE,CZECH REPUBLIC

[2] ACAD SCI CZECH REPUBL,J HEYROVSKY INST PHYS CHEM,CR-18223 PRAGUE 8,CZECH REPUBLIC

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 509卷 / 01期

关键词：

4-silaspiro[3,3]heptane; 2-silaallene; homogeneous decomposition; laser; poly(2-silaallene);

D O I：

10.1016/0022-328X(95)05797-S

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Continuous-wave CO2 laser-photosensitized (SF6) decomposition of 4-silaspiro[3,3]heptane is dominated by the transient formation and polymerization of 2-silaallene. The first experimental evidence for 2-silaallene has been achieved via scavenging with alcohols ROH (R = CH3, CF3CH2) to afford dialkoxy(dimethyl)silanes, (RO)(2)Si(CH3)(2). ESCA analysis of the polymer demonstrates SiC2 stoichiometry and indicates the incorporation of oxygen, which may be explained by reaction of the residual Si=C bonds with air.

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页码：73 / 76

页数：4

相关论文

共 31 条

[1] THEORETICAL INVESTIGATIONS ON SOME C2SIH4 ISOMERS [J].

BARTHELAT, JC ;

TRINQUIER, G ;

BERTRAND, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (14) :3785-3789

[2] NEW SILENE REARRANGEMENTS FROM A STUDY OF THE MECHANISM OF SILACYCLOPENTENE FORMATION FROM [3.3]SILASPIROCYCLOHEPTANE [J].

BARTON, TJ ;

BURNS, GT ;

GSCHNEIDNER, D .

ORGANOMETALLICS, 1983, 2 (01) :8-11

[3] HYPOTHESES ON FORMATION OF 1ST DIGONAL SILICON INTERMEDIATE DURING PYROLYSIS [J].

BERTRAND, G ;

MANUEL, G ;

MAZEROLLES, P .

TETRAHEDRON, 1978, 34 (13) :1951-1956

[4] EFFICIENT LASER-INDUCED GENERATION AND POLYMERIZATION OF THE HIGHLY UNSATURATED COMPOUND DIETHYNYLSILENE IN THE GAS-PHASE [J].

CUKANOVA, D ;

POLA, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 453 (01) :17-20

[5] KINETICS OF ADDITION OF 2-METHYL-2-SILAPROPENE TO HYDROGEN-CHLORIDE, HYDROGEN BROMIDE, AND OXYGEN [J].

DAVIDSON, IMT ;

DEAN, CE ;

LAWRENCE, FT .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (02) :52-53

[6] LASER-POWERED DECOMPOSITION OF SPIRO[2.N]ALKANES (N = 2-5) [J].

FAJGAR, R ;

POLA, J .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (27) :7709-7717

[7] MOLECULAR AND ELECTRONIC-STRUCTURE OF SILADIIMIDE AND OTHER ALLENIC X=Y=X COMPOUNDS [J].

GORDON, MS ;

SCHMIDT, MW ;

KOSEKI, S .

INORGANIC CHEMISTRY, 1989, 28 (11) :2161-2163

[8] RELATIVE STABILITY OF MULTIPLE BONDS TO SILICON - AN ABINITIO STUDY OF C2SIH4 ISOMERS [J].

GORDON, MS ;

KOOB, RD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (11) :2939-2944

[9] ESCA STUDY OF ORGANOSILICON COMPOUNDS [J].

GRAY, RC ;

CARVER, JC ;

HERCULES, DM .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1976, 8 (05) :343-357

[10] FORMATION AND PROPERTIES OF UNSTABLE INTERMEDIATES CONTAINING MULTIPLE P-PI-P PI-BONDED GROUP-4B METALS [J].

GUSELNIKOV, LE ;

NAMETKIN, NS .

CHEMICAL REVIEWS, 1979, 79 (06) :529-577

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