pH-switchable silver nanoprism growth pathways

被引:216
作者
Xue, Can
Mirkin, Chad A.
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA
关键词
nanoparticles; nanostructures; optical force; photoexcitation; plasmon resonance; SHAPE-CONTROLLED SYNTHESIS; GOLD NANOPARTICLES; METAL NANOPARTICLES; OPTICAL-PROPERTIES; DNA; NANOCRYSTALS; PARTICLES;
D O I
10.1002/anie.200604637
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) A pHunction of pH: The silver nanoprism fusion process can be turned on and off as a function of the pH value during photochemical synthesis. With appropriate pH regulation (see TEM images, middle and right), one can achieve excellent control over the nanoprism edge length with a fixed 10-nm thickness and the corresponding plasmon bands, which span the visible and NIR range (see extinction spectra, left). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2036 / 2038
页数:3
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