Energy transfer in π-conjugated polymers:: Interchain vs. intrachain processes in polyindenofluorene

被引：14

作者：

Beljonne, D

Pourtois, G

Shuai, Z

Hennebicq, E

Scholes, GD

Brédas, JL

机构：

[1] Univ Arizona, Dept Chem, Tucson, AZ 85721 USA

[2] Univ Mons, Ctr Rech Elect & Photon Mol, B-7000 Mons, Belgium

[3] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China

[4] Univ Toronto, Lash Miller Chem Labs, Toronto, ON M5S 3H6, Canada

来源：

SYNTHETIC METALS | 2003年 / 137卷 / 1-3期

关键词：

semi-empirical models; optical absorption and emission spectroscopy; conjugated polymers;

D O I：

10.1016/S0379-6779(02)01071-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The energy transfer processes taking place in conjugated polymers are investigated by means of correlated quantum-chemical calculations applied to polyindenofluorene. The calculations go beyond the usual point-dipole model approximation and account for geometric relaxation phenomena in the excited state prior to energy migration. The results indicate a higher efficiency of the interchain transfer process, which is mainly due to larger electronic coupling matrix elements.

引用

收藏

页码：1369 / 1371

页数：3

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