Towards biological supramolecular chemistry:: A variety of pocket-templated, individual metal oxide cluster nucleations in the cavity of a Mo/W-storage protein

被引：79

作者：

Schemberg, Joerg

Schneider, Klaus

Demmer, Ulrike

Warkentin, Eberhard

Mueller, Achim

Ermler, Ulrich

机构：

[1] Univ Bielefeld, Fac Chem, D-33501 Bielefeld, Germany

[2] Max Planck Inst Biophys, D-60438 Frankfurt, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 14期

关键词：

polyoxometalates; proteins; supramolecular chemistry; template synthesis; tungsten;

D O I：

10.1002/anie.200604858

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Create and protect: The cavity shell of a molybdenum/tungsten-storage protein acts as a polytopic host for several types of polyoxotungstate guests, which occur as individual clusters (one shown: yellow W, red O, ribbons protein) that are noncovalently or weakly bonded to the host. The formation of the guests is templated by the specific functionalities of the protein pockets. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：2408 / 2413

页数：6

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