Spectroscopic study of non-amphiphilic 9-phenyl fluorene assembled in Langmuir-Blodgett films in two different matrices: dimer and excimer formation

被引:12
作者
Acharya, S
Bhattacharjee, D
Talapatra, GB [1 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Spect, Kolkata 700032, W Bengal, India
[2] Tripura Univ, Dept Phys, Suryamaninagar 799130, Tripura, India
关键词
D O I
10.1016/S0009-2614(03)00369-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Multilayered Langmuir-Blodgett (LB) films at different mole fractions of 9-phenyl fluorene (9PF) have been prepared using two different matrices viz. stearic acid (SA) and polymethyl methacrylate (PMMA). The spectroscopic properties of the mixed LB films, solution and microcrystal have been compared using absorption, steady-state fluorescence, and excitation spectroscopy. The spectroscopic studies give evidence of formation of excimeric sites in 9PF-SA LB films, while formation of dimeric species along with the excimeric sites have been evidenced in case of 9PF-PMMA LB films. (C) 2003 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:97 / 103
页数:7
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