Noncovalently connected frameworks with nanoscale channels assembled from a tethered polyoxometalate-pyrene hybrid

被引：172

作者：

Song, Yu-Fei ^{[1
]}

Long, De-Liang ^{[1
]}

Cronin, Leroy ^{[1
]}

机构：

[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 21期

关键词：

organic-inorganic hybrid compounds; polyoxometalates; porous materials; pyrene; supramolecular interactions;

D O I：

10.1002/anie.200604734

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Porous POMs: Crystallization of a manganese-Anderson- type polyoxometalate (POM) derivatized with two pyrene moieties in the presence of tetrabutylammonium cations produces a nanoporous material with butterfly-shaped channels (O red, Mo green, C black, H white, N blue). The network is held together by very weak C-H⋯O=Mo interactions, but is stable to 240°C and can absorb up to 12 wt% chlorobenzene. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3900 / 3904

页数：5

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