Perfect complementarity in the fitting of two homochiral heterodonor ligands around a nickel(II) centre: an 'intramolecular embrace'

被引：12

作者：

Bray, KL ^{[1
]}

Butts, CP ^{[1
]}

Lloyd-Jones, GC ^{[1
]}

Murray, M ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 09期

关键词：

D O I：

10.1039/a801170b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homochiral form of the complex [('P,N')(2)Ni](2+) ('P,N' is a phosphino-heteroatom bidentate ligand) has been found to be more stable than its heterochiral analogue due to a 'fitting' of the two 'P,N' ligands about the Ni that is reminiscent of an 'intramolecular embrace'.

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页码：1421 / 1422

页数：2

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