Novel odd/even effect of alkylene chain length on the photopolymerizability of organogelators

被引：61

作者：

Aoki, K ^{[1
]}

Kudo, M ^{[1
]}

Tamaoki, N ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058565, Japan

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 22期

关键词：

D O I：

10.1021/ol048364+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Starting from diactylene diacarboxylic acids, we have synthesized a series of photopolymerizable organogelators that possess simple amide structures, different alkylene chain lengths, and either optically active or racemic 3,7-dimethyl-1-octylamine units. The alkylene chain length of these compounds exhibits a prominent odd/even effect with respect to the photopolymerization in the gel state and is accompanied by a stereostructural effect on the gelation ability.

引用

页码：4009 / 4012

页数：4

共 23 条

[1] Abdallah DJ, 2000, ADV MATER, V12, P1237
[2] CANTOW HJ, 1984, POLYDIACETYLENES
[3] Frisch M.J., 2016, Gaussian 16 Revision C. 01. 2016, V01
[4] Low molecular-mass gelators with diyne functional groups and their unpolymerized and polymerized gel assemblies
George, M
Weiss, RG
[J]. CHEMISTRY OF MATERIALS, 2003, 15 (15) : 2879 - 2888
[5] GOSNITZER E, 2002, ARCH PHARM PHARM MED, V11, P535
[6] Organogel from L-leucine-containing surfactant in nonpolar solvents
Hanabusa, K
Kobayashi, H
Suzuki, M
Kimura, M
Shirai, H
[J]. COLLOID AND POLYMER SCIENCE, 1998, 276 (03) : 252 - 259
[7] New gelators based on 2-amino-2-phenylethanol: Close gelator-chiral structure relationship
Hanabusa, K
Maesaka, Y
Kimura, M
Shirai, H
[J]. TETRAHEDRON LETTERS, 1999, 40 (12) : 2385 - 2388
[8] Preparation of new robust organic gels by in situ cross-link of a bis(diacetylene) gelator
Inoue, K
Ono, Y
Kanekiyo, Y
Hanabusa, K
Shinkai, S
[J]. CHEMISTRY LETTERS, 1999, (05) : 429 - 430
[9] PREPARATION OF LAYERED DIACETYLENES AS A DEMONSTRATION OF STRATEGIES FOR SUPRAMOLECULAR SYNTHESIS
KANE, JJ
LIAO, RF
LAUHER, JW
FOWLER, FW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (48) : 12003 - 12004
[10] Self-assembled organogels formed by mono-chain L-alanine derivatives
Luo, XH
Liu, B
Liang, YQ
[J]. CHEMICAL COMMUNICATIONS, 2001, (17) : 1556 - 1557

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