Ni0-catalyzed regio- and stereoselective coupling reaction of Me3B, isoprene, and aldehydes

被引:47
作者
Kimura, M [1 ]
Shibata, K [1 ]
Koudahashi, Y [1 ]
Tamaru, Y [1 ]
机构
[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan
关键词
aldehydes; boron and compounds; dienes; nickel and compounds;
D O I
10.1016/S0040-4039(00)01079-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
In the presence of Ni(acac)(2) (0.1 equiv.), the three components of trimethylborane, isoprene, and aromatic and aliphatic aldehydes combine to produce 1-substituted 3-methyl-3-hexenols (3) in good yield and with high regio- and stereoselectivity (E:Z>13:1). (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
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页码:6789 / 6793
页数:5
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