Ni0-catalyzed regio- and stereoselective coupling reaction of Me3B, isoprene, and aldehydes

被引：47

作者：

Kimura, M ^{[1
]}

Shibata, K ^{[1
]}

Koudahashi, Y ^{[1
]}

Tamaru, Y ^{[1
]}

机构：

[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 35期

关键词：

aldehydes; boron and compounds; dienes; nickel and compounds;

D O I：

10.1016/S0040-4039(00)01079-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of Ni(acac)(2) (0.1 equiv.), the three components of trimethylborane, isoprene, and aromatic and aliphatic aldehydes combine to produce 1-substituted 3-methyl-3-hexenols (3) in good yield and with high regio- and stereoselectivity (E:Z>13:1). (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：6789 / 6793

页数：5

共 27 条

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