Microprobe study of the effect of Li intercalation on the structure of graphite

被引:125
作者
Kostecki, R [1 ]
McLarnon, F [1 ]
机构
[1] Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA
关键词
Li intercalation; graphite anode; carbon disordering; solid electrolyte interphase (SEI);
D O I
10.1016/S0378-7753(03)00287-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structural stability of graphite electrodes in Li-ion cells, which were cycled at room temperature and 60 degreesC was investigated. We observed gradual structural degradation of the graphite, which was most pronounced on the electrode surface but also extended into the bulk of the electrode. Graphite particles close to the Cu current collector remained almost unchanged, whereas those close to the electrode/electrolyte interface suffered significant structural damage. Structural degradation of the graphite led to an increased anode surface reactivity vs. the electrolyte. A thick layer of inorganic products from side reactions was observed on the disordered carbon areas of the anode. (C) 2003 Elsevier Science B.V All rights reserved.
引用
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页码:550 / 554
页数:5
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