Sonochemical preparation and characterization of europium oxide doped in and coated on ZrO2 and yttrium-stabilized zirconium (YSZ)

被引:54
作者
Gedanken, A [1 ]
Reisfeld, R
Sominski, E
Palchik, O
Koltypin, Y
Panczer, G
Gaft, M
Minti, H
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[2] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91940 Jerusalem, Israel
[3] Univ Lyon 1, Lab Physicochim Mat Luminescents, UMR 5620 CNRS, F-69622 Villeurbanne, France
[4] Open Univ, Phys Grp, IL-61392 Tel Aviv, Israel
[5] Open Univ, Geol Grp, IL-61392 Tel Aviv, Israel
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2000年 / 104卷 / 30期
关键词
D O I
10.1021/jp000652+
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ultrasound radiation was used to prepare Eu2O3 dd in zirconia and yttrium-stabilized zirconium (YSZ) nanoparticles. Europium oxide was also coated on the surface of submicron spherical zirconia and YSZ, which were fabricated by wet chemical methods. The coating process also used ultrasonic waves. Time decay measurements of the doped and coated materials were conducted using a pulsed laser source. Lifetimes <1.1 ms radiative lifetime of the Eu3+ ion were detected for the doped and coated as-prepared materials. When the doped and coated samples were annealed at 700 degrees C, longer lifetimes were measured. The shorter lifetimes were attributed to concentration quenching.
引用
收藏
页码:7057 / 7065
页数:9
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