Dendritic stars by ring-opening-metathesis polymerization from ruthenium-carbene initiators

被引：65

作者：

Gatard, S

Nlate, S

Cloutet, E

Bravic, G

Blais, JC

Astruc, D ^{[1
]}

机构：

[1] Univ Bordeaux 1, CNRS, UMR 5802, LCOO, F-33405 Talence, France

[2] Univ Bordeaux 1, ENSCPB, LCPO, F-33607 Pessac, France

[3] ICMCB, F-33608 Pessac, France

[4] Univ Paris 06, CNRS, UMR 7613, LCSOB, F-75252 Paris, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 04期

关键词：

carbenes; dendrimers; metathesis; polymerization; ruthenium;

D O I：

10.1002/anie.200390137

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A star in the making: A new rutheniumcarbene complex has been synthesized by using a diphosphane ligand that models the dendritic branch of poly (diphosphane) dendrimers. First, second, and third generation metallodendrimers derived from diaminobutane polyamines, with 4, 8, and 16 ruthenium-containing branches, respectively, have been synthezised and shown to initiate the ring-opening-metathesis polymerization (ROMP) of norbornene at room temperature to form metallodendritic polymer stars (see scheme; P = PCy2).

引用

页码：452 / +

页数：6

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