A supramolecular triarm star polymer from a homotritopic tris(crown ether) host and a complementary monotopic paraquat-terminated polystyrene guest by a supramolecular coupling method

被引:173
作者
Huang, F [1 ]
Nagvekar, DS [1 ]
Slebodnick, C [1 ]
Gibson, HW [1 ]
机构
[1] Virginia Polytech Inst & State Univ, Dept Chem, Blacksburg, VA 24061 USA
关键词
D O I
10.1021/ja0438516
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The first supramolecular star polymer based on pseudorotaxane host-guest complexation was prepared from statistical complexation of a homotritopic tris(crown ether) host and monotopic paraquat-terminated polystyrene guest in solution. The formation of this supramolecular star polymer was confirmed by proton NMR characterization and viscosity studies. Copyright © 2005 American Chemical Society.
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页码:484 / 485
页数:2
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