Synthesis and structure of di(NON-azoxy)formals and some related N-alkyl-N'-alkoxydiazene N-oxides

被引：16

作者：

Zyusin, IN

Nechiporenko, GN

Golovina, NI

Trofimova, RF

Loginova, NV

机构：

[1] Inst. Chem. Phys. in Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka, Moscow

来源：

RUSSIAN CHEMICAL BULLETIN | 1997年 / 46卷 / 08期

关键词：

di(NON-azoxy)formals; N-alkyl-N'-alkoxydiazene N-oxides; N-nitrosohydroxylamines; X-ray diffraction analysis; synthesis;

D O I：

10.1007/BF02505678

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of di(NON-azoxy)formals and some related N-alkyl-N'-alkoxydiazene N-oxides were prepared by the reaction of N-nitrosohydroxylamine salts with dihaloalkanes. The dependence of the yield of di(methyl-NON-azoxy)formal on the reaction conditions and the nature of the cation was studied. The structure of di(methyl-NON-azoxy)formal and di(phenyl-NON-azoxy)formal as well as of the copper tert-butylnitrosohydroxylaminate was established by X-ray diffraction analysis.

引用

页码：1421 / 1429

页数：9

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