Synthesis of new biosynthetically important diarylheptanoids and their oxa- and fluoro-analogues by three different strategies

被引：20

作者：

Baranovsky, A ^{[1
]}

Schmitt, B ^{[1
]}

Fowler, DJ ^{[1
]}

Schneider, B ^{[1
]}

机构：

[1] Max Planck Inst Chem Ecol, D-07745 Jena, Germany

来源：

SYNTHETIC COMMUNICATIONS | 2003年 / 33卷 / 06期

关键词：

diarylheptanoids; alcol reaction; Wittig reaction; Wittig-horner reaction;

D O I：

10.1081/SCC-120016367

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Wittig, aldol and Wittig-Horner reactions have been used to synthesize new diarylheptanoids, which are putative intermediates in phenylphenalenone biosynthesis in plants. The Wittig-Horner approach was most suitable and gave significantly higher yields in comparison with other methods.

引用

收藏

页码：1019 / 1045

页数：27

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