Cross-metathesis with acrylonitrile and applications to fatty acid derivatives

被引：50

作者：

Bruneau, Christian ^{[1
]}

Fischmeister, Cedric ^{[1
]}

Miao, Xiaowei ^{[1
]}

Malacea, Raluca ^{[1
]}

Dixneuf, Pierre H. ^{[1
]}

机构：

[1] Univ Rennes 1, CNRS, UMR 6226, F-35042 Rennes, France

来源：

EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY | 2010年 / 112卷 / 01期

关键词：

Acrylonitrile; Cross-metathesis; Ruthenium catalysts; Unsaturated fats; RENEWABLE RAW-MATERIALS; PRODUCTIVE CATALYST TURNOVERS; RUTHENIUM-BASED CATALYST; OLEFIN METATHESIS; FUNCTIONALIZED OLEFINS; CHEMICAL-INDUSTRY; METHYL ACRYLATE; GRUBBS CATALYST; HIGH CONVERSION; NATURAL OILS;

D O I：

10.1002/ejlt.200900105

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

In this minireview, we report on the state of the art concerning the cross-metathesis of acrylonitrile with olefins. A special focus is given to catalytic conditions that are suitable for medium-size and long-chain aliphatic model substrates. The recent applications of this metathesis reaction to fatty acid derivatives to generate fatty nitriles and bifunctional products are considered. They represent very attractive transformations for the access to N-containing monomers and functional intermediates for the chemical industry from renewable raw materials.

引用

页码：3 / 9

页数：7

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