Asymmetric tandem reactions based on nitroalkenes:: a one-pot construction of functionalized chiral bicycles by a three-component reaction

被引：16

作者：

Avalos, M ^{[1
]}

Babiano, R ^{[1
]}

Cintas, P ^{[1
]}

Jiménez, JL ^{[1
]}

Palacios, JC ^{[1
]}

Silva, MA ^{[1
]}

机构：

[1] Univ Extremadura, Fac Ciencias, Dept Quim Organ, E-06071 Badajoz, Spain

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 04期

关键词：

D O I：

10.1039/a708222c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Asymmetric tandem cycloaddition of a chiral carbohydrate nitroalkene with ethyl vinyl ether in the presence of electron-withdrawing alkenes produces a facile assembly of bicyclic systems, which can further be selectively cleaved to give homologated carbohydrates.

引用

页码：459 / 460

页数：2

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