Small-angle X-ray scattering from micellar solutions of gemini surfactants

被引:25
作者
Aswal, VK [1 ]
Goyal, PS
De, S
Bhattacharya, S
Amenitsch, H
Bernstorff, S
机构
[1] Bhabha Atom Res Ctr, Div Solid State Phys, Bombay 400085, Maharashtra, India
[2] Bhabha Atom Res Ctr, Bombay Ctr, DAEF, IUC, Bombay 400085, Maharashtra, India
[3] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
[4] Austrian Acad Sci, Inst Biophys & Xray Struct Res, A-8010 Graz, Austria
[5] Sincrotrone Trieste, I-34012 Trieste, Italy
关键词
D O I
10.1016/S0009-2614(00)01043-5
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In an earlier work, we had studied small-angle neutron scattering (SANS) from micellar solutions of bis-cationic C16H33N+ (CH3)(2)-(CH2)(m)-N+ (CH3)(2)C16H33, 2Br(-) gemini surfactants, referred to as 16-m-16. 2Br(-), for several spacer lengths. This Le;ter reports the results of small-angle X-ray scattering (SAXS) experiments on the above system for spacer lengths of m = 3, 4 and 12. It is seen that SAXS distributions are qualitatively different from the SANS distributions. These experiments show that a combined SANS and SAXS study can be used for obtaining information on the counterion distribution around the micelles, (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:336 / 340
页数:5
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