Bulk-Type All Solid-State Batteries with 5 V Class LiNi0.5Mn1.5O4 Cathode and Li10GeP2S12 Solid Electrolyte

被引：233

作者：

Oh, Gwangseok ^{[1
]}

Hirayama, Masaaki ^{[1
]}

Kwon, Ohmin ^{[1
]}

Suzuki, Kota ^{[1
]}

Kanno, Ryoji ^{[1
]}

机构：

[1] Tokyo Inst Technol, Midori Ku, G1-1,4259,Nagatsuda, Yokohama, Kanagawa 2268502, Japan

来源：

CHEMISTRY OF MATERIALS | 2016年 / 28卷 / 08期

基金：

日本科学技术振兴机构;

关键词：

ELECTROCHEMICAL PROPERTIES; LITHIUM BATTERIES; PERFORMANCE; STORAGE; ION; INTERCALATION; SPINEL; LICOO2;

D O I：

10.1021/acs.chemmater.5b04940

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

All solid-state batteries are of key importance in the development of next-generation energy storage devices with high energy density. Herein, we report the fabrication and operation of bulk-type 5 V-class all solid-state batteries consisting of LiNi0.5Mn1.5O4 cathode, Li10GeP2S12 solid-electrolyte, and Li metal anode. The 1st discharge capacity is about 80 mAh g(-1). with an average voltage of 4.3 V. The discharge capacity gradually decreases during the subsequent cycles. X-ray diffraction and electrochemical impedance spectroscopy measurements reveal that the capacity fading results from the growth of a resistive interfacial layer on the cathode composite. The development of suitable conductive additive and sulfide solid electrolyte materials is essential for the development of high-voltage all solid-state batteries.

引用

页码：2634 / 2640

页数：7

共 33 条

[1]

[Anonymous], 2012, ANGEW CHEM-GER EDIT, DOI DOI 10.1002/ANGE.201106998

[2] Phase transition kinetics of LiNi0.5Mn1.5O4 electrodes studied by in situ X-ray absorption near-edge structure and X-ray diffraction analysis [J].

Arai, Hajime ;

Sato, Kenji ;

Orikasa, Yuki ;

Murayama, Haruno ;

Takahashi, Ikuma ;

Koyama, Yukinori ;

Uchimoto, Yoshiharu ;

Ogumi, Zempachi .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (35) :10442-10449

[3] Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].

Armstrong, AR ;

Bruce, PG .

NATURE, 1996, 381 (6582) :499-500

[4] Mechanism for limited 55°C storage performance of Li1.05Mn1.95O4 electrodes [J].

Du Pasquier, A ;

Blyr, A ;

Courjal, P ;

Larcher, D ;

Amatucci, G ;

Gérand, B ;

Tarascon, JM .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (02) :428-436

[5] Study of LiNi0.5Mn1.5O4 synthesized via a chloride-ammonia co-precipitation method: Electrochemical performance, diffusion coefficient and capacity loss mechanism [J].

Fang, X. ;

Ding, N. ;

Feng, X. Y. ;

Lu, Y. ;

Chen, C. H. .

ELECTROCHIMICA ACTA, 2009, 54 (28) :7471-7475

[6] Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes [J].

Hartmann, Pascal ;

Leichtweiss, Thomas ;

Busche, Martin R. ;

Schneider, Meike ;

Reich, Marisa ;

Sann, Joachim ;

Adelhelm, Philipp ;

Janek, Juergen .

JOURNAL OF PHYSICAL CHEMISTRY C, 2013, 117 (41) :21064-21074

[7]

Jing Li W. J., 2015, FUNTAI OYOBI FUNMATS, V62, P548

[8]

Kamaya N, 2011, NAT MATER, V10, P682, DOI [10.1038/NMAT3066, 10.1038/nmat3066]

[9] Discharge Performance of All-Solid-State Battery Using a Lithium Superionic Conductor Li10GeP2S12 [J].

Kato, Yuki ;

Kawamoto, Koji ;

Kanno, Ryoji ;

Hirayama, Masaaki .

ELECTROCHEMISTRY, 2012, 80 (10) :749-751

[10] Comparative study of LiNi0.5Mn1.5O4-δ and LiNi0.5Mn1.5O4 cathodes having two crystallographic structures:: Fd(3)over-barm and P4332 [J].

Kim, JH ;

Myung, ST ;

Yoon, CS ;

Kang, SG ;

Sun, YK .

CHEMISTRY OF MATERIALS, 2004, 16 (05) :906-914

← 1 2 3 4 →