Synthesis of a novel doubly strapped zinc porphyrin and its recognition property for anions

被引：13

作者：

Bao, Xiaoping ^{[1
]}

Zhang, Hao ^{[1
]}

Zhang, Zhi ^{[1
]}

Wu, Lei ^{[1
]}

Li, Zaoying ^{[1
]}

机构：

[1] Wuhan Univ, Coll Chem & Mol Sci, Wuhan 430072, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 06期

基金：

中国国家自然科学基金;

关键词：

doubly strapped zinc porphyrin; hydrogen bonds; Lewis acidic binding; anion receptor;

D O I：

10.1016/j.inoche.2007.03.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel doubly strapped zinc porphyrin (2) was synthesized, characterized and studied as anion receptor. It showed a very high affinity and selectivity for H2PO4-, F- and AcO- over other anions by combining Lewis acidic binding site (Zn2+) with NHs of the urea groups. In contrast, free base porphyrin (1) and ZnTPP did not show detectable affinities for all the anions examined. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：728 / 730

页数：3

共 20 条

[1] Selective anion recognition by novel 5,10,15,20-tetrakis(o-ferrocenyl-carbonylaminophenyl-substituted) zinc metalloporphyrin receptors [J].

Beer, PD ;

Drew, MGB ;

Jagessar, R .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (05) :881-886

[2] Transition metal and organometallic anion complexation agents [J].

Beer, PD ;

Hayes, EJ .

COORDINATION CHEMISTRY REVIEWS, 2003, 240 (1-2) :167-189

[3]

Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO

[4]

2-G

[5] ION-RESPONSIVE FLUORESCENT COMPOUNDS .4. EFFECT OF CATION BINDING ON THE PHOTOPHYSICAL PROPERTIES OF A COUMARIN LINKED TO MONOAZA-CROWN AND DIAZA-CROWN ETHERS [J].

BOURSON, J ;

POUGET, J ;

VALEUR, B .

JOURNAL OF PHYSICAL CHEMISTRY, 1993, 97 (17) :4552-4557

[6] PICKET-FENCE PORPHYRINS - SYNTHETIC MODELS FOR OXYGEN BINDING HEMOPROTEINS [J].

COLLMAN, JP ;

GAGNE, RR ;

REED, CA ;

HALBERT, TR ;

LANG, G ;

ROBINSON, WT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1427-1439

[7] 3-DIMENSIONAL STRUCTURE OF THE CATALYTIC SUBUNIT OF PROTEIN SERINE/THREONINE PHOSPHATASE-1 [J].

GOLDBERG, J ;

HUANG, HB ;

KWON, YG ;

GREENGARD, P ;

NAIRN, AC ;

KURIYAN, J .

NATURE, 1995, 376 (6543) :745-753

[8] Neutral ligands for selective chloride anion complexation:: (α,α,α,α)-5,10,15,20-tetrakis(2-(arylurea)phenyl)porphyrins [J].

Jagessar, RC ;

Shang, MY ;

Scheidt, WR ;

Burns, DH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) :11684-11692

[9] (cis)5,10,15,20-tetrakis[2(arylurea)phenyl]porphyrins: novel neutral ligands for remarkably selective and exceptionally strong chloride anion complexation in (CD3)(2)SO [J].

Jagessar, RC ;

Burns, DH .

CHEMICAL COMMUNICATIONS, 1997, (17) :1685-1686

[10] Carbamate-appended Zn-porphyrin: a neutral receptor for anions [J].

Kim, YH ;

Hong, JI .

TETRAHEDRON LETTERS, 2000, 41 (22) :4419-4423

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