Kinetic arrest originating in competition between attractive interaction and packing force

被引:33
作者
Foffi, G [1 ]
Zaccarelli, E
Sciortino, F
Tartaglia, P
Dawson, KA
机构
[1] Natl Univ Ireland Univ Coll Dublin, Dept Chem, Irish Ctr Colloid Sci & Biomat, Dublin 4, Ireland
[2] Univ Rome La Sapienza, Dipartimento Fis, I-00185 Rome, Italy
[3] Ist Nazl Fis Mat, Unita Roma La Sapienza, I-00185 Rome, Italy
关键词
colloidal systems; Baxter model; disordered systems; glass transition; mode coupling theory;
D O I
10.1023/A:1018660200206
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We discuss the situation where attractive and repulsive portions of the interparticle potential both contribute significantly to glass formation. We introduce the square-well potential as prototypical model for this situation, and reject the Baxter model as a useful model for comparison to experiment on glasses, based on our treatment within mode coupling theory. We present explicit results for various well widths, and show that, for narrow wells, there is a useful analytical formula that would be suitable for experimentalists working in the field of colloidal science. We raise the question as to whether, in a more exact treatment, the sticky-sphere limit might have an infinite glass transition temperature or a high but finite one.
引用
收藏
页码:363 / 376
页数:14
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ZACCARELLI E, 1999, THESIS U