Mechanochemical synthesis of magnesium aluminate spinel powder at room temperature

被引:79
作者
Domanski, D [1 ]
Urretavizcaya, G [1 ]
Castro, FJ [1 ]
Gennari, FC [1 ]
机构
[1] Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Rio Negro, Argentina
关键词
D O I
10.1111/j.1151-2916.2004.tb06354.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
MgAl2O4 spinel was successfully synthesized using a mechanochemical route that avoided the formation and calcination of its precursors at high temperatures. The method involved a single step in which gamma-Al2O3-MgO, AlO(OH)-MgO, and alpha-Al2O3-MgO mixtures were milled at room temperature under air atmosphere. The formation of MgAl2O4 occurred faster with gamma-Al2O3 than with AlO(OH) or alpha-Al2O3. After 140 h, the mechanochemical treatment of the gamma-Al2O3-MgO mixture yielded 99% of MgAl2O4.
引用
收藏
页码:2020 / 2024
页数:5
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