Orbital control of the color and excited state properties of formylated and fluorinated derivatives of azulene

被引：94

作者：

Shevyakov, SV

Li, HR

Muthyala, R

Asato, AE

Croney, JC

Jameson, DM

Liu, RSH

机构：

[1] Univ Hawaii, Dept Chem, Honolulu, HI 96822 USA

[2] Univ Hawaii, Dept Cell & Mol Biol, Honolulu, HI 96822 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2003年 / 107卷 / 18期

关键词：

D O I：

10.1021/jp021605f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New azulene derivatives containing resonantly electron withdrawing formyl and resonantly electron donating fluorine substituents on the seven- as well as the five-member ring have been prepared. Systematic color changes as a result of perturbation of HOMO, LUMO, and LUMO + 1 energies were discussed. Corresponding excited-state properties related to S-2-fluorescence were determined.

引用

页码：3295 / 3299

页数：5

共 24 条

[1] The azulene S-1 state decays via a conical intersection: A CASSCF study with MMVB dynamics [J].