Electrochemical polymerization of anthracene in boron trifluoride diethyl etherate

被引：46

作者：

Fan, B ^{[1
]}

Qu, LT ^{[1
]}

Shi, GQ ^{[1
]}

机构：

[1] Tsing Hua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2005年 / 575卷 / 02期

基金：

中国国家自然科学基金;

关键词：

electrochemistry; polyanthracene; fluorescence;

D O I：

10.1016/j.jelechem.2004.10.002

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Anthracene has been electrochemically polymerized in the electrolyte of boron trifluoride diethyl etherate. The oxidation potential of anthracene monomer in this medium was measured as 0.7 V approximately (versus Ag\AgCl). Polyanthracene (PAn) with 417 repeating anthracene units was obtained and its conductivity was measured as around 0.1 S/cm. This value is about 100 times that of the PAn reported previously. The structure of the polymer has been investigated by UV/Vis, infrared and Raman spectroscopies. The resulting product was partly soluble in usual organic solvents such as tetrahydrofuran and chloroform. The soluble part of the polymer is a strong blue light emitter. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：287 / 292

页数：6

共 21 条

[1]

BAUMGARTEN M, 1992, ANGEW CHEM, V104, P482

[2] Catalytic polymerization of anthracene oil with aluminium trichloride [J].

Fernández, AL ;

Granda, M ;

Bermejo, J ;

Menéndez, R .

CARBON, 1999, 37 (08) :1247-1255

[3]

HINTERHOFER O, 1980, MAKROMOL CHEM, V181, P67

[4] Electrochemical polymerization of naphthalene in the electrolyte of boron trifluoride diethyl etherate containing trifluoroacetic acid and polyethylene glycol oligomer [J].

Huang, ZM ;

Qu, LT ;

Shi, GQ ;

Chen, F ;

Hong, XY .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 556 :159-165

[5] Electrochemical polymerization of β-naphthalene sulfonic acid in the mixed electrolyte of boron trifluoride diethyl etherate and trifluoroacetic acid [J].

Huang, ZM ;

Shi, GQ ;

Qu, LT ;

Hong, XY .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 544 :41-46

[6] Interaction between thiophene and solvated Lewis acids and the low-potential electrochemical deposition of a highly anisotropic conducting polythiophene film [J].

Jin, S ;

Xue, G .

MACROMOLECULES, 1997, 30 (19) :5753-5757

[7] LADDER POLYMERS AS NEW POLYMERIC CONDUCTORS [J].

KIM, OK .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1984, 105 (1-4) :161-173

[8] High-quality poly(p-phenylene) film prepared by electrochemical polymerization of benzene at a stainless steel electrode [J].

Li, C ;

Shi, GQ ;

Liang, YQ ;

Ye, W ;

Sha, ZL .

POLYMER, 1997, 38 (20) :5023-5026

[9] POLYARYLENES AND POLY(ARYLENEVINYLENE)S .14. SYNTHESIS OF SOLUBLE POLY(2,6-DI-TERT-BUTYL-9,10-ANTHRYLENE) VIA REDUCTIVE COUPLING OF QUINONES WITH LITHIOANTHRYLENES [J].

MULLER, U ;

MANGEL, T ;

MULLEN, K .

MACROMOLECULAR RAPID COMMUNICATIONS, 1994, 15 (01) :45-53

[10] THE ELECTROCHEMICAL POLYMERIZATION OF ANTHRACENE [J].

SATOH, M ;

UESUGI, F ;

TABATA, M ;

KANETO, K ;

YOSHINO, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (12) :979-980

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