Inner core structure responds to communication between nanocapsule walls

被引:101
作者
Cave, GWV
Antesberger, J
Barbour, LJ
McKinlay, RM
Atwood, JL [1 ]
机构
[1] Univ Missouri, Dept Chem, Columbia, MO 65211 USA
[2] Univ Stellenbosch, Dept Chem, ZA-7602 Matieland, South Africa
关键词
calixarenes; cavitands; host-guest systems; hydrogen bonds; nanostructures; self-assembly;
D O I
10.1002/anie.200460711
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The facile self-assembly of six pyrogallol[4]arene molecules leads to a globular truncated octahedron, which encapsulates a guest cluster consisting of ethyl acetate and water molecules (see scheme). The interactions between host capsules can be controlled by derivatization of the exterior surface of the capsule.
引用
收藏
页码:5263 / 5266
页数:4
相关论文
共 24 条
[1]  
Atwood J.L., 2001, J SUPRAMOLECULAR CHE, V1, P131
[2]   Organization of the interior of molecular capsules by hydrogen bonding [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (08) :4837-4841
[3]   Hydrogen-bonded molecular capsules are stable in polar media [J].
Atwood, JL ;
Barbour, LJ ;
Jerga, A .
CHEMICAL COMMUNICATIONS, 2001, (22) :2376-2377
[4]   Spontaneous formation of hexameric resorcinarene capsule in chloroform solution as detected by diffusion NMR [J].
Avram, L ;
Cohen, Y .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (51) :15148-15149
[5]  
BARBOUR LJ, 2003, MCAVITY PROGRAM DETE
[6]   Determining the position of the cell division plane [J].
Canman, JC ;
Cameron, LA ;
Maddox, PS ;
Straight, A ;
Tirnauer, JS ;
Mitchison, TJ ;
Fang, GW ;
Kapoor, TM ;
Salmon, ED .
NATURE, 2003, 424 (6952) :1074-1078
[7]  
Cave GWV, 2001, EUR J ORG CHEM, V2001, P3227
[8]   Host-guest encapsulation of materials by assembled virus protein cages [J].
Douglas, T ;
Young, M .
NATURE, 1998, 393 (6681) :152-155
[9]  
Gerkensmeier T, 1999, EUR J ORG CHEM, V1999, P2257
[10]  
Lodish H.F., 2013, Molecular cell biology