Weak ferromagnetism in a three-dimensional manganese(II) azido complex, [Mn(4,4′-bipy)(N3)2]n (bipy = bipyridine)

被引：121

作者：

Han, S

Manson, JL

Kim, J

Miller, JS

机构：

[1] Kongju Natl Univ, Dept Chem, Chungnam 314701, South Korea

[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 18期

关键词：

D O I：

10.1021/ic000307z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Low-field magnetic studies on [Mn(4,4'-bipyridine)-(N-3)(2)](n) reveal a spontaneous magnetization below ordering temperatures of 42.5 K, due to a transition to a weak ferromagnetic ground state.

引用

页码：4182 / +

页数：5

共 40 条

[1]

[Anonymous], NATO ASI SERIES

[2] Ferrimagnetic behavior of multiple phases and solvates of (meso-tetrakis(4-chlorophenyl)porphinato)manganese(III) tetracyanoethenide, [MnTClPP]+[TCNE]•-.: Enhancement of magnetic coupling by thermal annealing [J].

Brandon, EJ ;

Rittenberg, DK ;

Arif, AM ;

Miller, JS .

INORGANIC CHEMISTRY, 1998, 37 (13) :3376-3384

[3] Influence of pseudohalide ions on the molecular structure and magnetic properties of the manganese(II)-bipyrimidine-pseudohalide system [J].

Cortes, R ;

Urtiaga, MK ;

Lezama, L ;

Pizarro, JL ;

Arriortua, MI ;

Rojo, T .

INORGANIC CHEMISTRY, 1997, 36 (22) :5016-5021

[4] Alternating ferro- and antiferromagnetic interactions in honeycomb-like layers of an azidomanganese(II) compound [J].

Cortes, R ;

Lezama, L ;

Pizarro, JL ;

Arriortua, MI ;

Rojo, T .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1996, 35 (16) :1810-1812

[5] CRYSTAL-STRUCTURE AND SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF 2 CIS-AZIDO CATENAS OF NICKEL(II) - CIS-CATENA-MU-N3)[NI(BIPY)2](X) (X=CLO4, PF6) [J].

CORTES, R ;

URTIAGA, K ;

LEZAMA, L ;

PIZARRO, JL ;

GONI, A ;

ARRIORTUA, MI ;

ROJO, T .

INORGANIC CHEMISTRY, 1994, 33 (18) :4009-4015

[6]

CORTES R, 1996, MOL BASED MAGNETIC M, P187

[7] A THERMODYNAMIC THEORY OF WEAK FERROMAGNETISM OF ANTIFERROMAGNETICS [J].

DZYALOSHINSKY, I .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1958, 4 (04) :241-255

[8] Magnetic studies on mu-azido polynuclear nickel(II) compounds with the 222-tet ligand. Crystal structure of (mu-N-3)(2)[Ni(222-tet)](2)(BPh4)(2)(222-tet=triethylenetetramine) and EXAFS structural characterization of the triangular compounds (mu-N-3)(3)[Ni(222-tet)](3)(X)(3) (X=PF6,(-), ClO4,(-)) [J].

Escuer, A ;

Castro, I ;

Mautner, F ;

ElFallah, MS ;

Vicente, R .

INORGANIC CHEMISTRY, 1997, 36 (21) :4633-4640

[9] A new two-dimensional manganese(II)-azide polymer. Synthesis, structure and magnetic properties of [{Mn(minc)(2)(N-3)(2)}(n)] (minc equals methyl isonicotinate) [J].

Escuer, A ;

Vicente, R ;

Goher, MAS ;

Mautner, FA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22) :4431-4434

[10] STRUCTURE AND MAGNETIC-BEHAVIOR OF A NEW 2-DIMENSIONAL ANTIFERROMAGNETIC MANGANESE(II)-MU-1,3-AZIDO SYSTEM [J].

ESCUER, A ;

VICENTE, R ;

GOHER, MAS ;

MAUTNER, FA .

INORGANIC CHEMISTRY, 1995, 34 (23) :5707-&

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