Enyne metathesis catalyzed by ruthenium carbene complexes

被引：353

作者：

Poulsen, CS ^{[1
]}

Madsen, R ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Chem, Bldg 201, DK-2800 Lyngby, Denmark

来源：

SYNTHESIS-STUTTGART | 2003年 / 01期

关键词：

alkenes; alkynes; carbene complexes; catalysis; Diels-Alder reactions; enynes; metathesis; ring closure; ruthenium; tandem reactions;

D O I：

10.1055/s-2003-36243

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enyne metathesis combines an alkene and an alkyne into a 1,3-diene. The first enyne metathesis reaction catalyzed by a ruthenium carbene complex was reported in 1994. This review covers the advances in this transformation during the last eight years with particular emphasis on methodology development and synthetic applications.

引用

页码：1 / 18

页数：18

共 125 条

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