Synthesis, structure, and bonding in polyiodide and metal iodide-iodine systems

被引:766
作者
Svensson, PH [1 ]
Kloo, L [1 ]
机构
[1] Royal Inst Technol, Dept Inorgan Chem, S-10044 Stockholm, Sweden
关键词
D O I
10.1021/cr0204101
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polyiodide compounds exhibit a vast diversity of structures, preferentially of low-dimensional character, with conducting properties ranging from insulators to metals. Increasing structural complexity is attributed to the increase in I2 content of the compounds and through the interaction between the fundamental building blocks. The fundamental knowledge of polyiodide materials is now such that the application of polyiodide systems into interesting directions involving electronic and magnetic materials, host-guest compounds and as electrolytes for use in electrochemical devices, such as batteries and solar cells, is unprecedented.
引用
收藏
页码:1649 / 1684
页数:36
相关论文
共 342 条
[1]   X-RAY CRYSTAL-STRUCTURE OF THE 1ST QUATERNARY 1-BICYCLO[1.1.1]PENTANE SALT - THE SHORTEST NONBONDING CARBON CARBON INTERACTION DOCUMENTED [J].
ADCOCK, JL ;
GAKH, AA ;
POLLITTE, JL ;
WOODS, C .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (10) :3980-3981
[2]   ORGANIC SEMICONDUCTORS WITH HIGH CONDUCTIVITY .1. COMPLEXES BETWEEN POLYCYCLIC AROMATIC HYDROCARBONS AND HALOGENS [J].
AKAMATU, H ;
INOKUCHI, H ;
MATSUNAGA, Y .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1956, 29 (02) :213-218
[3]   Linear pentaiodide in the radical cation salt of a tetrathiafulvalene bisannulated macrocycle [J].
Akutagawa, T ;
Abe, Y ;
Nezu, Y ;
Nakamura, T ;
Kataoka, M ;
Yamanaka, A ;
Inoue, K ;
Inabe, T ;
Christensen, CA ;
Becher, J .
INORGANIC CHEMISTRY, 1998, 37 (10) :2330-2331
[4]  
Alcock N.W., 1972, ADV INORG CHEM, V15, P1, DOI DOI 10.1016/S0065-2792(08)60016-3
[5]   MOLECULAR AND POLYMERIC COMPOUNDS RESULTING FROM LEWIS-ACID INTERACTIONS WITH [CPMO(MU-S)N-T-BU]2 [J].
ALLSHOUSE, J ;
HALTIWANGER, RC ;
ALLURED, V ;
DUBOIS, MR .
INORGANIC CHEMISTRY, 1994, 33 (12) :2505-2506
[6]   Adduct formation between (Ph(3)SbI)(2)O and I-2 [J].
Almond, MJ ;
Drew, MGB ;
Rice, DA ;
Salisbury, G ;
Taylor, MJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (02) :265-269
[7]   Raman spectra of molecular crystals I. Chlorine, bromine, and iodine [J].
Anderson, A. ;
Sun, T. S. .
CHEMICAL PHYSICS LETTERS, 1970, 6 (06) :611-616
[8]  
[Anonymous], EXTENDED LINEAR CHAI
[9]  
[Anonymous], HOMOATOMIC RINGS CHA
[10]   PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [I-5+][ASF6-] AND ELECTRONIC-STRUCTURE OF THE I-5+ CATION [J].
APBLETT, A ;
GREIN, F ;
JOHNSON, JP ;
PASSMORE, J ;
WHITE, PS .
INORGANIC CHEMISTRY, 1986, 25 (04) :422-426