RRT: The regularized resolvent transform for high-resolution spectral estimation

被引:20
作者
Chen, JH [1 ]
Shaka, AJ [1 ]
Mandelshtam, VA [1 ]
机构
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
基金
美国国家科学基金会;
关键词
D O I
10.1006/jmre.2000.2176
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
A new numerical expression, called the regularized resolvent transform (RRT), is presented. RRT is a direct transformation of the truncated time-domain data into a frequency-domain spectrum and is suitable for high-resolution spectral estimation of multidimensional time signals. One of its forms, under the condition that the signal consists only of a finite sum of damped sinusoids, turns out to be equivalent to the exact infinite time discrete Fourier transformation. RRT naturally emerges from the filter diagonalization method, although no diagonalization is required. In RRT the spectrum at each frequency s is expressed in terms of the resolvent R(s)(-1) of a small data matrix R(s), that is constructed from the time signal. Generally, R is singular, which requires certain regularization. In particular, the Tikhonov regularization, R-1 approximate to [(RR)-R-dagger + q(2)]R--1(dagger) with regularization parameter q, appears to be computationally both efficient and very stable. Numerical implementation of RRT is very inexpensive because even for extremely large data sets the matrices involved are small. RRT is demonstrated using model 1D and experimental 2D NMR signals. (C) 2000 Academic Press.
引用
收藏
页码:129 / 137
页数:9
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