Characterization of two new stable block copolymer mesophases by synchrotron small-angle scattering

被引：26

作者：

Burger, C ^{[1
]}

Micha, MA ^{[1
]}

Oestreich, S ^{[1
]}

Forster, S ^{[1
]}

Antonietti, M ^{[1
]}

机构：

[1] Max Planck Inst Kolloid & Grenzflachenforsch, D-14513 Teltow, Germany

来源：

EUROPHYSICS LETTERS | 1998年 / 42卷 / 04期

关键词：

D O I：

10.1209/epl/i1998-00266-0

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Block copolymers made of polystyrene and fluorinated blocks represent a new class of polymers with a very strong incompatibility between the two blocks. They exhibit new stable block copolymer mesophases which are not considered in the phase diagrams of diblock copolymers in the strong and super-strong segregation regime. The solid-state structures of two polymers with different compositions are characterized by synchrotron small-angle X-ray scattering and transmission electron microscopy, thus proving the existence of a quadratically perforated layer phase and a 2D phase of sanidically degenerated cylinders.

引用

页码：425 / 429

页数：5

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