A Robust Polyionized Hydrogel with an Unprecedented Underwater Anti-Crude-Oil-Adhesion Property

被引:497
作者
Gao, Shoujian [1 ,2 ]
Sun, Jichao [3 ]
Liu, Pingping [1 ,2 ,4 ]
Zhang, Feng [1 ,2 ]
Zhang, Wenbin [1 ,2 ]
Yuan, Shiling [3 ]
Li, Jingye [5 ]
Jin, Jian [1 ,2 ]
机构
[1] Chinese Acad Sci, I Lab, Suzhou 215123, Peoples R China
[2] Chinese Acad Sci, CAS Ctr Excellence Nanosci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China
[3] Shandong Univ, Key Lab Colloid & Interface Chem, Jinan 250100, Peoples R China
[4] Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
[5] Chinese Acad Sci, Shanghai Inst Appl Phys, CAS Ctr Excellence TMSR Energy Syst, Shanghai 201800, Peoples R China
基金
中国国家自然科学基金;
关键词
IN-WATER EMULSIONS; OIL/WATER SEPARATION; SUPEROLEOPHOBIC SURFACES; ENGINEERING MATERIALS; PVDF MEMBRANES; COATED MESH; FABRICATION; SPILL; REMOVAL; SPONGES;
D O I
10.1002/adma.201600417
中图分类号
O6 [化学];
学科分类号
070301 [无机化学];
摘要
A polyionized hydrogel polymer (sodium polyacrylate-grafted poly(vinylidene fluoride) (PAAS-g-PVDF)) is fabricated via an alkaline-induced phase-inversion process. PAAS-g-PVDF coatings exhibit unprecedented anti-adhesion and self-cleaning properties to crude oils under an aqueous environment. A PAAS-g-PVDF-coated copper mesh can effectively separate a crude oil/water mixture with extremely high flux and high oil rejection driven by gravity, and is oil-fouling-free for long-term use.
引用
收藏
页码:5307 / +
页数:9
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