Ethylene oxide and propylene sulfide complexes of silver(I):: Synthesis and characterization of [HB(3,5-(CF3)2Pz)3]Ag(OC2H4) and [HB(3,5-(CF3)2Pz)3]Ag(SC3H6)

被引：29

作者：

Dias, HVR ^{[1
]}

Wang, ZY ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 16期

关键词：

D O I：

10.1021/ic991334w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and solid-state structures of [HB(3,5-(CF3)(2)PZ)(3)]Ag(OC2H4) and [HB(3,5-(CF3)(2)Pz)(3)]Ag-(SC3H6) are presented. The propylene sulfide ligand shows a relatively large tilt toward the [HB(3,5-(CF3)(2)-Pz)(3)]Ag moiety compared to the ethylene oxide ligand. [HB(3,5-(CF3)(2)Pz)(3)]Ag(OC2H4) and [HB(3,5-(CF3)(2)Pz)(3)]Ag(SC3H6) are rare examples of compounds featuring metal-epoxide and metal-thiirane bonding. [GRAPHICS]

引用

页码：3724 / +

页数：5

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