Ruthenium polyoxometalate water splitting catalyst: very fast hole scavenging from photogenerated oxidants

被引：144

作者：

Orlandi, Michele ^{[3
]}

Argazzi, Roberto ^{[4
]}

Sartorel, Andrea ^{[1
,2
]}

Carraro, Mauro ^{[1
,2
]}

Scorrano, Gianfranco ^{[1
,2
]}

Bonchio, Marcella ^{[1
,2
]}

Scandola, Franco ^{[3
]}

机构：

[1] Univ Padua, CNR, ITM, I-35131 Padua, Italy

[2] Univ Padua, Dept Chem Sci, I-35131 Padua, Italy

[3] Univ Ferrara, Dept Chem, Interuniv Res Ctr Chem Convers Solar Energy, I-44121 Ferrara, Italy

[4] CNR, ISOF, Sez Ferrara, I-44121 Ferrara, Italy

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 18期

关键词：

ELECTRON-TRANSFER; OXYGEN EVOLUTION; OXIDATION; COMPLEXES; EFFICIENT; FAMILY; DIMER;

D O I：

10.1039/b926823e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tetraruthenium polyoxometalate water oxidation catalyst 1 performs very fast hole scavenging from photogenerated Ru(III) polypyridine complexes, both in homogeneous solution and at a sensitized nanocrystalline TiO2 surface.

引用

页码：3152 / 3154

页数：3

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