Pheromone syntheses: A tropical approach. Enantioselective synthesis of the (2R,6S,10S) and (2S,6S,10S) isomers of methyl 2,6,10-trimethyldodecanoate

被引：24

作者：

Ferreira, JTB ^{[1
]}

Zarbin, PHG ^{[1
]}

机构：

[1] UNIV FED SAO CARLOS,DEPT QUIM,LAB SINTESE PROD NAT,BR-13565905 SAO CARLOS,SP,BRAZIL

来源：

BIOORGANIC & MEDICINAL CHEMISTRY | 1996年 / 4卷 / 03期

基金：

巴西圣保罗研究基金会;

关键词：

pheromone; synthesis; Euschistus obscurus; Euschistus heros; dodecanoate; methyl 2,6,10-trimethyl;

D O I：

10.1016/0968-0896(96)00015-6

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The enantioselective syntheses of two stereoisomers, (2R,6S,10S) and (2S,6S,10S), of methyl 2,6,10-trimethyldodecanoate, out of eight possible isomers, are described, employing the stereoselective hydroboration of (-)-isopulegol (2) and (+)-neo-isopulegol (2a) as the key reaction. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：381 / 388

页数：8

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