Modeling capacity fade in lithium-ion cells

被引:153
作者
Liaw, BY [1 ]
Jungst, RG [1 ]
Nagasubramanian, G [1 ]
Case, HL [1 ]
Doughty, DH [1 ]
机构
[1] Sandia Natl Labs, Albuquerque, NM 87185 USA
基金
美国能源部;
关键词
lithium-ion battery; capacity fade; equivalent-circuit model simulation; battery life prediction; thermal aging;
D O I
10.1016/j.jpowsour.2004.08.017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Battery life is an important, yet technically challenging, issue for battery development and application. Adequately estimating battery life requires a significant amount of testing and modeling effort to validate the results. Integrated battery testing and modeling is quite feasible today to simulate battery performance, and therefore applicable to predict its life. A relatively simple equivalent-circuit model (ECM) is used in this work to show that such an integrated approach can actually lead to a high-fidelity simulation of a lithium-ion cell's performance and life. The methodology to model the cell's capacity fade during thermal aging is described to illustrate its applicability to battery calendar life prediction. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:157 / 161
页数:5
相关论文
共 22 条
[1]   Universal battery parameterization to yield a non-linear equivalent circuit valid for battery simulation at arbitrary load [J].
Barsoukov, E ;
Kim, JH ;
Yoon, CO ;
Lee, H .
JOURNAL OF POWER SOURCES, 1999, 83 (1-2) :61-70
[2]   RELAXATION PHENOMENA IN LITHIUM-ION-INSERTION CELLS [J].
FULLER, TF ;
DOYLE, M ;
NEWMAN, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (04) :982-990
[3]   SIMULATION AND OPTIMIZATION OF THE DUAL LITHIUM ION INSERTION CELL [J].
FULLER, TF ;
DOYLE, M ;
NEWMAN, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (01) :1-10
[4]   Micro-macroscopic coupled modeling of batteries and fuel cells - II. Application to nickel-cadmium and nickel-metal hydride cells [J].
Gu, WB ;
Wang, CY ;
Liaw, BY .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1998, 145 (10) :3418-3427
[5]   Accelerated calendar and pulse life analysis of lithium-ion cells [J].
Jungst, RG ;
Nagasubramanian, G ;
Case, HL ;
Liaw, BY ;
Urbina, A ;
Paez, TL ;
Doughty, DH .
JOURNAL OF POWER SOURCES, 2003, 119 :870-873
[6]  
JUNGST RG, 2002, P 40 POW SOURC C CHE
[7]   A frequency-domain approach to dynamical modeling of electrochemical power sources [J].
Karden, E ;
Buller, S ;
De Doncker, RW .
ELECTROCHIMICA ACTA, 2002, 47 (13-14) :2347-2356
[8]   Correlation of Arrhenius behaviors in power and capacity fades with cell impedance and heat generation in cylindrical lithium-ion cells [J].
Liaw, BY ;
Roth, EP ;
Jungst, RG ;
Nagasubramanian, G ;
Case, HL ;
Doughty, DH .
JOURNAL OF POWER SOURCES, 2003, 119 :874-886
[9]   Integrated battery simulation and characterization [J].
Liaw, BY ;
Yang, XG ;
Bethune, K .
SOLID STATE IONICS, 2002, 152 :51-59
[10]   Advanced integrated battery testing and simulation [J].
Liaw, BY ;
Bethune, KP ;
Yang, YG .
JOURNAL OF POWER SOURCES, 2002, 110 (02) :330-340