Host-guest complexation effect of 2,3,6-tri-O-methyl-β-cyclodextrin on a C60-porphyrin light-to-photocurrent conversion system

被引：46

作者：

Ikeda, A ^{[1
]}

Hatano, T

Konishi, T

Kikuchi, J

Shinkai, S

机构：

[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan

[2] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Higashi Ku, Fukuoka 8128581, Japan

来源：

TETRAHEDRON | 2003年 / 59卷 / 19期

关键词：

fullerenes; calixarenes; porphyrins; cyclodextrins; photocurrent;

D O I：

10.1016/S0040-4020(03)00417-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In a light-to-photocurrent conversion system based on a C-60-porphyrin bilayer prepared by electrostatic alternate adsorption, porphyrin units in a porphyrin polymer have been isolated by cyclodextrin utilizing the host-guest interaction. In this system, a high quantum yield was achieved by suppression of self-quenching of porphyrin units. (C) 2003 Elsevier Science Ltd. All rights reserved.

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页码：3537 / 3540

页数：4

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