Spin-orbit effects in photodissociation of sodium iodide

Ab initio configuration interaction calculations of the electronic binding energies, spin-orbit coupling matrix elements and transition dipole moments of NaI are presented. The results are used to construct adiabatic and diabatic representations of the 0(+) molecular states relevant to predissociation. The dynamics of photopredissociation is elucidated by multichannel time-dependent wave packet propagation in the diabatic representation. Specific features associated with the spatial and temporal evolution of the wave packet are ascribed to those observed in femtosecond pump-probe experiments. In particular, the rate of decay of the electronically excited NaI* complex is found to be in close agreement with time-resolved experimental studies. Partial photoabsorption cross sections for the production of iodine atoms in the ground (P-2(3/2)) and excited (P-2(1/2)) spin-orbit states are calculated and found to peak at excitation wavelengths of 322 and 263 nm, respectively, in accord with experimental data. (C) 2000 American Institute of Physics. [S0021-9606(00)01228-9].