Design of strongly NLO-active molecularly-based ferromagnets

被引：60

作者：

Bernard, S

Yu, P

Coradin, T

Riviere, E

Nakatani, K

Clement, R

机构：

[1] UNIV PARIS 11, CHIM INORGAN LAB, URA 420, F-91405 ORSAY, FRANCE

[2] ECOLE NORMALE SUPER, PPSM, URA 1906, F-94235 CACHAN, FRANCE

来源：

ADVANCED MATERIALS | 1997年 / 9卷 / 12期

关键词：

D O I：

10.1002/adma.19970091212

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Molecule-based ferromagnets that exhibit strong second-harmonic generation (SHG) are presented here for the first time. The strategy for producing such materials-replace the ''innocent'' bulky cations (C) in the C[M'M(ox)(3)] family of bimetallic magnets (M' is e.g. Mn and M = Cr-III or Fe-III: the Figure shows the structure) by hyperpolarizable cationic chromophores-is described and X-ray, magnetic, and SHG results are reported.

引用

页码：981 / +

页数：1

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