Efficient heterogeneous aerobic oxidation of amines by a supported ruthenium catalyst

被引：328

作者：

Yamaguchi, K ^{[1
]}

Mizuno, N ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 13期

关键词：

amines; heterogeneous catalysis; oxidation; oxygen; ruthenium;

D O I：

10.1002/anie.200250779

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An inexpensive supported ruthenium catalyst (Ru/Al2O3) can be used to convert a broad range of primary (see scheme) and secondary amines into the corresponding nitriles and imines in high yields using either dioxygen or air as oxidants. The catalyst can be recycled and reused with no detectable loss of ruthenium and without an observed reduction in catalytic activity.

引用

页码：1480 / 1483

页数：4

共 33 条

[1] The role of catalysis in the design, development, and implementation of green chemistry [J].

Anastas, PT ;

Bartlett, LB ;

Kirchhoff, MM ;

Williamson, TC .

CATALYSIS TODAY, 2000, 55 (1-2) :11-22

[2] Catalysed aerobic dehydrogenation of amines and an X-ray crystal structure of a bis(benzylamine) ruthenium(II) porphyrin species [J].

Bailey, AJ ;

James, BR .

CHEMICAL COMMUNICATIONS, 1996, (20) :2343-2344

[3] CATALYSIS - AUTOXIDATION IN PRESENCE OF ACTIVE COBALT OXIDE [J].

BELEW, JS ;

GARZA, C ;

MATHIESO.JW .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (11) :634-&

[4] DIRECTIVE EFFECTS IN AROMATIC SUBSTITUTION .30. ELECTROPHILIC SUBSTITUENT CONSTANTS [J].

BROWN, HC ;

OKAMOTO, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (18) :4979-4987

[5]

CAPDEVIELLE P, 1989, SYNTHESIS-STUTTGART, P453

[6]

CENINI S, 1982, J MOL CATAL, V15, P297, DOI 10.1016/0304-5102(82)80023-0

[7] EFFICIENT RUTHENIUM-CATALYZED TRANSFER HYDROGENATION OF KETONES BY PROPAN-2-OL [J].

CHOWDHURY, RL ;

BACKVALL, JE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (16) :1063-1064

[8]

Connors K. A., 1990, CHEM KINETICS STUDY, DOI [10.1002/0470845015.cta014, DOI 10.1002/0470845015.CTA014]

[9] BETA-ELIMINATION FROM TRANSITION-METAL AMIDES [J].

DIAMOND, SE ;

MARES, F .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 142 (03) :C55-C57

[10] NICKEL PEROXIDE OXIDATION OF ORGANIC COMPOUNDS [J].

GEORGE, MV ;

BALACHANDRAN, KS .

CHEMICAL REVIEWS, 1975, 75 (04) :491-519

← 1 2 3 4 →