Persistent phosphinyl radicals from a bulky diphosphine: an example of a molecular jack-in-the-box

被引：87

作者：

Hinchley, SL

Morrison, CA

Rankin, DWH

Macdonald, CLB

Wiacek, RJ

Cowley, AH

Lappert, MF

Gundersen, G

Clyburne, JAC

Power, PP

机构：

[1] Univ Edinburgh, Dept Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA

[3] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9RH, E Sussex, England

[4] Univ Oslo, Dept Chem, N-0315 Oslo, Norway

[5] Acadia Univ, Dept Chem, Wolfville, NS B0P 1X0, Canada

[6] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 20期

关键词：

D O I：

10.1039/b004889p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the phosphinyl radical, (P) over dot R-2 [R = CH(SiMe3)(2)], has been determined by gas-phase electron diffraction (GED) together with ab initio molecular orbital calculations, and that of the corresponding diphosphine, (PR2)(2), has been established by X-ray crystallography; the diphosphine behaves as an energy storage reservoir.

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页码：2045 / 2046

页数：2

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