Reversible C-C bond formation: solid state structure of the aldol-like addition product of adamantanone to a 1,5-diazapentadienyllithium, and its solution state retro-aldol dissociation

被引：11

作者：

Ball, LJ

Dickie, AP

Mair, FS

Middleton, DA

Pritchard, RG

机构：

[1] Univ Manchester, Dept Chem, Manchester M60 1QD, Lancs, England

[2] Univ Manchester, Dept Biomol Sci, Manchester M60 1QD, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 06期

关键词：

D O I：

10.1039/b211745b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Analysis of crystals of the lithium complex of the tripodal ligand formed upon addition of adamantanone to a 1,5 diazapentadienyllithium complex reveals a long C-C bond which ruptures upon dissolution in non-co-ordinating solvents.

引用

页码：744 / 745

页数：2

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