Anion detection driven by a surprising internal hydrogen-bonding association in a dinuclear Rhenium(I) complex

被引：29

作者：

Pelleteret, Diane ^{[1
]}

Fletcher, Nicholas C. ^{[1
]}

Doherty, Andrew P. ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

来源：

INORGANIC CHEMISTRY | 2007年 / 46卷 / 11期

关键词：

D O I：

10.1021/ic700452k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A neutral dinuclear rhenium(I) bipyridinetricarbonyl bromide complex has been investigated with a range of anions, giving a remarkable binding affinity for dihydrogenphosphate. These studies highlight that anion sensing can be achieved with structurally simple species provided that the compound adopts an unconventional conformation, through, for example, intramolecular hydrogen bonding in solution.

引用

页码：4386 / 4388

页数：3

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