Use of elemental metals in different grade of activation for phthalocyanine preparation

被引：15

作者：

Kharisov, BI ^{[1
]}

Coronado, CEC ^{[1
]}

Cerda, KPC ^{[1
]}

Méndez, UO ^{[1
]}

Guzmán, JAJ ^{[1
]}

Patlán, LAR ^{[1
]}

机构：

[1] Univ Autonoma Nuevo Leon, Monterrey 66450, Mexico

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 12期

关键词：

phthalocyanines; transition metals; activated metals; synthesis at low temperature;

D O I：

10.1016/j.inoche.2004.10.006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis of non-substituted metal phthalocyaninates starting from phthalonitrile in various non-aqueous solvents in presence of a series of elemental metals in different grade of activation is described. Special attention is paid to phthalocyanine formation at relatively low temperatures (0-50 degreesC). In case of use of various forms of activated and non-active nickel, it is shown that its most active form causes rapid PcNi formation at 0-25 degreesC without addition of CH3ONa. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1269 / 1272

页数：4

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