Aqueous suspension polymerization of isobutene initiated by 1,2-C6F4[B(C6F5)2]2

被引：70

作者：

Lewis, SP

Henderson, LD

Chandler, BD

Parvez, M

Piers, WE ^{[1
]}

Collins, S

机构：

[1] Univ Akron, Dept Polymer Sci, Akron, OH 44325 USA

[2] Univ Calgary, Dept Chem, Calgary, AB, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 01期

关键词：

D O I：

10.1021/ja0445387

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lewis acidic, chelating diborane 1 forms stable oxonium acids 2 in the presence of excess MeOH or water. Diborane 1 is shown to be an effective co-initiator for the suspension polymerization of isobutene in aqueous media at sufficiently low temperatures. Poly(isobutene) or butyl rubber is obtained at moderate to high conversion and with Mw < 200 K and PDI ≈ 2 under these conditions. Copyright © 2005 American Chemical Society.

引用

页码：46 / 47

页数：2

共 39 条

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