Sulfur dioxide gas detection by reversible η1-SO2-Pt bond formation as a novel application for periphery functionalised metallo-dendrimers

被引:75
作者
Albrecht, M
Gossage, RA
Spek, AL
van Koten, G
机构
[1] Univ Utrecht, Debye Res Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands
[2] Univ Utrecht, Bijvoet Ctr Biomol Res Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands
关键词
D O I
10.1039/a708630j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multimetallics such as dendrimer 3 which are functionalised at their periphery with platinum(II) metal centres reversibly absorb SO2 to yield macromolecules with significantly enhanced solubility characteristics and drastic colour changes; properties which make these compounds highly active sensors for milligram quantities of toxic SO2 gas.
引用
收藏
页码:1003 / 1004
页数:2
相关论文
共 22 条