Preparation of polystyrene/polyaniline blends by in situ polymerization technique and their morphology and electrical property

被引:51
作者
Bae, WJ
Jo, WH [1 ]
Park, YH
机构
[1] Seoul Natl Univ, Hyperstructured Organ Mat Res Ctr, Sch Mat Sci & Engn, Seoul 151742, South Korea
[2] Sungkyunkwan Univ, Dept Text Engn, Coll Engn, Suwon 440746, South Korea
关键词
polyaniline; polystyrene; in situ polymerization technique; blend; electrical; conductivity;
D O I
10.1016/S0379-6779(02)00451-4
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Electrically conducting polystyrene/polyaniline blends were prepared by in situ polymerization technique (method I), and simple solution blending (method II). Electrical conductivities of the blends prepared by method I are higher than those of the corresponding blends prepared by method II or any other methods. This is attributed to the fact that the blends prepared by method I have higher crystallinity and better homogeneous morphology than the blends prepared by method II. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:239 / 244
页数:6
相关论文
共 22 条
[1]   Synthesis of high molecular weight polyaniline at low temperatures [J].
Adams, PN ;
Laughlin, PJ ;
Monkman, AP .
SYNTHETIC METALS, 1996, 76 (1-3) :157-160
[2]  
Angelopoulos M, 1996, MATER RES SOC SYMP P, V413, P637
[3]   LiCl induced morphological changes in polyaniline base and their effect on the electronic properties of the doped form [J].
Angelopoulos, M ;
Liao, YH ;
Furman, B ;
Graham, T .
MACROMOLECULES, 1996, 29 (08) :3046-3049
[4]  
Bai X., 1993, J ELECTROCHEM SOC, V115, P8447
[5]   THERMAL-PROPERTIES OF POLYANILINE AND POLY(ANILINE-CO-O-ETHYLANILINE) [J].
CONKLIN, JA ;
HUANG, SC ;
HUANG, SM ;
WEN, TL ;
KANER, RB .
MACROMOLECULES, 1995, 28 (19) :6522-6527
[6]  
DAO LH, 1989, SYNTHETIC MET, V29, pE377
[7]  
Goh SH, 1998, J APPL POLYM SCI, V68, P1839
[8]  
Jousseaume V, 1998, J APPL POLYM SCI, V67, P1205, DOI 10.1002/(SICI)1097-4628(19980214)67:7<1205::AID-APP6>3.0.CO
[9]  
2-K
[10]   A STUDY OF MICROWAVE TRANSMISSION, REFLECTION, ABSORPTION, AND SHIELDING EFFECTIVENESS OF CONDUCTING POLYPYRROLE FILMS [J].
KAYNAK, A ;
UNSWORTH, J ;
CLOUT, R ;
MOHAN, AS ;
BEARD, GE .
JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 54 (03) :269-278