Insights into the mechanism of the Negishi reaction:: ZnRX versus ZnR2 reagents

被引：84

作者：

Casares, Juan A. ^{[1
]}

Espinet, Pablo ^{[1
]}

Fuentes, Beatriz ^{[1
]}

Salas, Gorka ^{[1
]}

机构：

[1] Univ Valladolid, Fac Ciencias, E-47071 Valladolid, Spain

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 12期

关键词：

D O I：

10.1021/ja070235b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The observation that their transmetalations with trans-[PdRfCl(PPh3)(2)] (Rf = fluoroaryl) give stereoselectively a different isomer of [PdRfMe(PPh3)(2)] suggests that Negishi reactions with ZnRX or ZnR2 could show very different evolutions.

引用

页码：3508 / +

页数：3

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